/ Home
/ SUBMISSION

/ The BJOC
/ Diamond Open Access
/ Journal Statistics
/ Editorial Board
/ Community
/ Call for papers

/ Latest Articles
/ Most accessed
/ Thematic issues
/ Volumes
/ Authors

/ Alerts

/ TWITTER
/ LINKEDIN
/ Mastodon
/ RSS FEED

Empty search

Article Type

Publication Date Range

Search Tips

This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.

Search Examples

aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)

BROWSE
Latest Articles
Most accessed
thematic issues
volumes
authors

BROWSE

Latest Articles Most Accessed Thematic Issues Volumes Authors

Author

1 article(s) from Veit, Philipp

On the mechanism of imine elimination from Fischer tungsten carbene complexes

Philipp Veit,
Christoph Förster and
Katja Heinze

Beilstein J. Org. Chem. 2016, 12, 1322–1333, doi:10.3762/bjoc.12.125

PDF

Graphical Abstract

Scheme 1: Imine formation and isomerization reactions from NH carbene complexes Cr(CO)₅(E-2) (a) [27], Cr(CO)₅(E/Z...

Jump to Scheme 1

Scheme 2: Synthesis of W(CO)₅(E-2) from W(CO)₅(1^Et) [20,21] and aminoferrocene [40,41] with concomitant formation of E-1,2-...

Jump to Scheme 2

Scheme 3: Reaction pathways 1a/1b (migration–elimination) and 2a/2b (elimination–migration) for the formation...

Jump to Scheme 3

Scheme 4: Reaction pathways 3a/3b/3c (CO dissociation) for the formation of imine E-3 from W(CO)₅(E-2).

Jump to Scheme 4

Figure 1: DFT calculated oxidative addition/pseudorotation/reductive elimination pathway 3c from W(CO)₄(E-2) ...

Jump to Figure 1

Figure 2: DFT calculated geometries of the two hydrido intermediates cis(N,H)-W(CO)₄(H)(Z-15) and cis(C,H)-W(...

Jump to Figure 2

Scheme 5: Proposed reaction sequence from W(CO)₅(E-2) to W(CO)₅(PPh₃) in the presence of triphenylphosphane.

Jump to Scheme 5

Album

Supp Info

Full Research Paper

Published 27 Jun 2016

Full text

Other Beilstein-Institut Open Science Activities

/ Help / Support & Contact / Alerts / Privacy Policy / Terms & Conditions / Impressum